Emulsions containing crosslinked and non-crosslinked silicone polyethers

ABSTRACT

Emulsions are prepared by heating and polymerizing a mixture containing (i) a non-crosslinked silicone polyether; (ii) optionally, a cosurfactant which can be a monohydroxy alcohol, diol, triol, or glycol ether; (iii) an ≡Si—H containing polysiloxane; (iv) a mono-alkenyl polyether; (v) an α,ω-diene, α,ω-diyne, or α,ω-ene-yne; (vi) optionally, a silicone oil such as (a) a low molecular weight linear or cyclic volatile methyl siloxane, or (b) a low molecular weight linear or cyclic volatile or non-volatile alkyl or aryl siloxane; (vii) a platinum catalyst; and (viii) water.

CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This is a division of co-pending U.S. patent application Ser. No. 09/866,995, filed May 29, 2001.

FIELD OF THE INVENTION

[0002] This invention is related to emulsions and preparing emulsions using non-crosslinked silicone polyethers and crosslinked silicone polyethers. In a first embodiment, emulsions containing non-crosslinked silicone polyethers and crosslinked silicone polyethers are prepared by emulsion polymerization. In a second embodiment, emulsions containing non-crosslinked silicone polyethers and crosslinked silicone elastomers containing no oxyalkylene units are prepared mechanically.

BACKGROUND OF THE INVENTION

[0003] While U.S. Pat. No. 5,387,417 (Feb. 7, 1995) suggests using certain non-crosslinked silicone polyethers in combination with certain crosslinked silicone polyethers for preparing emulsions, the '417 patent does not teach preparing emulsions using emulsion polymerization, a first embodiment of the present invention.

[0004] In addition, where emulsions in the '417 patent are prepared mechanically, the '417 patent does not teach preparing mechanical emulsions with a non-crosslinked silicone polyether in combination with a crosslinked silicone elastomer containing no oxyalkylene units, a second embodiment of the invention. Further, and in this regard, the '417 patent does not teach preparing emulsions with a non-crosslinked silicone polyether in combination with a crosslinked silicone elastomer containing no oxyalkylene units, without application of any mechanical shearing force.

BRIEF SUMMARY OF THE INVENTION

[0005] In a first embodiment, the invention is directed to a method of preparing emulsions by heating and polymerizing a mixture containing (i) a non-crosslinked silicone polyether; (ii) optionally, a cosurfactant which can be a monohydroxy alcohol, diol, triol, or glycol ether; (iii) an ≡Si—H containing polysiloxane; (iv) a mono-alkenyl polyether; (v) an α,ω-diene, α,ω-diyne, or α,ω)-ene-yne; (vi) optionally, a silicone oil such as (a) a low molecular weight linear or cyclic volatile methyl siloxane, or (b) a low molecular weight linear or cyclic volatile or non-volatile alkyl or aryl siloxane; (vii) a platinum catalyst; and (viii) water.

[0006] The crosslinked silicone polyether is obtained as a result of polymerization of components (iii), (iv), and (v).

[0007] In a second embodiment, the invention is directed to a method of making oil-in-water emulsions by mixing (i) a non-crosslinked silicone polyether; (ii) a cosurfactant such as a monohydroxy alcohol, diol, triol, or glycol ether; and (iii) water; with (iv) a crosslinked silicone elastomer containing no oxyalkylene units prepared by reacting (a) an ≡Si—H containing polysiloxane; (b) an α,ω-diene, α,ω-diyne, or α,ω-ene-yne; (c) a silicone oil such as (I) a low molecular weight linear or cyclic volatile methyl siloxanes, or (II) a low molecular weight linear or cyclic volatile or non-volatile alkyl or aryl siloxane; and (d) a platinum catalyst.

[0008] The invention is also directed to emulsions prepared according to the methods of each of these embodiments.

[0009] These and other features of the invention will become apparent from a consideration of the detailed description.

DETAILED DESCRIPTION OF THE INVENTION

[0010] Non-Crosslinked Silicone Polyether (SPE) Surfactant

[0011] The non-crosslinked silicone polyether is generally water soluble or water dispersible. It can have a rake type structure wherein the polyoxyethylene or polyoxyethylene-polyoxypropylene copolymeric units are grafted onto the siloxane backbone, or the SPE can have an ABA block copolymeric structure wherein A represents the polyether portion and B the siloxane portion of an ABA structure.

[0012] Non-crosslinked silicone polyethers suitable for use herein have the formula MD_(0-1,000)D′₁₋₁₀₀M, most preferably the formula MD₀₋₅₀₀D′₁₋₅₀M, where M represents monofunctional unit R₃SiO_(1/2), D represents difunctional unit R₂SiO_(2/2), and D′ represents difunctional unit RR′SiO_(2/2). In these formulas, R is an alkyl group containing 1-6 carbon atoms or an aryl group, and R′ is an oxyalkylene containing moiety. The R′ groups may contain only oxyethylene (EO) units; a combination of oxyethylene (EO) and oxypropylene (PO) units; or a combination of oxyethylene (EO) units, oxypropylene (PO) units, and oxybutylene (BO) units. Preferred R′ groups include oxyalkylene units in the approximate ratio of EO₃₋₁₀₀PO₀₋₁₀₀, most preferably in the ratio EO₃₋₃₀PO₁₋₃₀.

[0013] R′ moieties typically includes a divalent radical such as —C_(m)H_(2m)— where m is 2-8 for connecting the oxyalkylene portion of R′ to the siloxane backbone. Such moieties also contain a terminating radical for the oxyalkylene portion of R′ such as hydrogen, hydroxyl, or an alkyl, aryl, alkoxy, or acetoxy group.

[0014] Non-crosslinked silicone polyethers useful herein can also be of a type having the formula M′D_(10-1,000)D′₀₋₁₀₀M′, most preferably the formula M′D₁₀₋₅₀₀D′₀₋₅₀M′, wherein M′ represents monofunctional unit R₂R′SiO_(1/2), D represents difunctional unit R₂SiO_(2/2), and D′ represents difunctional unit RR′SiO_(2/2). In these formulas, R can be an alkyl group containing 1-6 carbon atoms or an aryl group, and again R′ represents an oxyalkylene containing moiety. As noted previously, R′ groups typically contain only oxyethylene (EO) units or combinations of oxyethylene (EO) and oxypropylene (PO) units. Such R′ groups include these oxyalkylene units in the ratio EO₃₋₁₀₀PO₀₋₁₀₀, most preferably EO₃₋₃₀PO₁₋₃₀.

[0015] As also noted previously, R′ moieties typically include a divalent radical —C_(m)H_(2m)— where m is 2-8 for connecting the oxyalkylene portions of R′ to the siloxane backbone. In addition, the moiety R′ contains a terminating radical for oxyalkylene portions of R′ such as hydrogen, hydroxyl, an alkyl, aryl, alkoxy, or acetoxy group.

[0016] In addition, non-crosslinked silicone polyethers useful herein can having the formula MD_(0-1,000)D′₀₋₁₀₀D″_(1-1,00)M wherein D″ represents difunctional unit RR″SiO_(2/2), and R″ is an alkyl group containing 1-40 carbon atoms. M, D, D′, and R, are the same as defined above.

[0017] Table I shows some representative non-crosslinked silicone polyethers conforming to these formulas which can be used in preparing emulsions according to the invention. TABLE I Non-Crosslinked Nominal Structure of Non-Crosslinked Silicone Polyether Silicone Polyethers A MD_(8.6)D′_(3.6)M where R is —CH₃ and R′ is —(CH₂)₃(EO)₁₂OH B MD₁₀₈D′₁₀M where R is —CH₃ and R′ is —(CH₂)₃(EO)₁₀(PO)₄OH C M′D′₇₅M′ where R is —CH₃ and R′ is —(CH₂)₃(EO)₁₈(PO)₁₈OAc D M′D′₅₀M′ where R is —CH₃ and R′is —(CH₂)₃(EO)₁₈(PO)₁₈OH E M′D′₁₃M′ where R is —CH₃ and R′ is —(CH₂)₃(EO)₁₂OH F MD₂₂D′₂M where R is —CH₃ and R′ is —(CH₂)₃(EO)₁₂(PO)₁₂OH

[0018] Cosurfactant

[0019] Emulsions prepared according to the invention may contain a cosurfactant. The cosurfactant can be a compound such as a monohydroxy alcohol, a diol, a triol, or it can be a glycol ether. Some representative cosurfactants which can be used include 1-butanol, 1-pentanol, 1-decanol, 1-hexadecanol, ethylene glycol, propylene glycol, trimethylene glycol, glycerol, and di(ethylene) glycol hexyl ether. Most preferred are glycol ethers, which are available commercially from The Dow Chemical Company, Midland, Mich., under their trademark DOWANOL®.

[0020] ≡Si—H Containing Polysiloxane

[0021] The ≡Si—H polysiloxane is represented by compounds of the formula R₃SiO(R′₂SiO)_(a)(R″HSiO)_(b)SiR₃, compounds of the formula HR₂SiO(R′₂SiO)_(c)SiR₂H, or compounds of the formula HR₂SiO(R′2SiO)_(a)(R″HSiO)_(b)SiR₂H, and mixtures thereof. In the three formulas, R, R′, and R″, are alkyl groups with 1-6 carbon atoms; a is 0-250; b is 1-250; and c is 0-250.

[0022] The ≡Si—H containing polysiloxane can also comprise an alkylhydrogen cyclosiloxane or an alkylhydrogen-dialkyl cyclosiloxane copolymer, represented in general by the formula (R′₂SiO)_(a)(R″HSiO)_(b) where R′, R″, a, and b, are as defined above. Preferably, a is 0-7; and b is 3-10. Some representative compounds are (OSiMeH)₄, (OSiMeH)₃(OSiMeC₆H₁₃), (OSiMeH)₂(OSiMeC₆H₁₃)₂, and (OSiMeH)(OSiMeC₆H₁₃)₃, where Me is

[0023] —CH₃.

[0024] Mono-Alkenyl Polyether

[0025] The mono-alkenyl polyether is a compound of the formula CH₂═CH(CH₂)_(f)O(CH₂CH₂O)_(g)(CH₂CH₃CHO)_(h)T, or a compound of the formula CH₂═CH-Q-O(CH₂CH₂O)_(g)(CH₂CH₃CHO)_(h)T. In the formulas, T represents an end group, which can be hydrogen; a C1-C10 alkyl group such as methyl, ethyl, propyl, butyl, and decyl; an aryl group such as phenyl; or a C1-C20 acyl group such as acetyl, propionyl, butyryl, lauroyl, myristoyl, and stearoyl. Q is a divalent linking group containing unsaturation such as phenylene —C₆H₄—. The value of f is 1-6; g has a value of 4-30; and h can be zero or have a value of 1-100.

[0026] α,ω-Diene, α,ω-Diyne, or α,ω-Ene-Yne

[0027] Unsaturated hydrocarbons which can be used include α,ω)-dienes of the formula CH₂═CH(CH₂)_(d)CH═CH₂ where d is 1-20. Some representative α,ω)-dienes are 1,4-pentadiene;

[0028] 1,5-hexadiene; 1,6-heptadiene; 1,7-octadiene; 1,8-nonadiene; 1,9-decadiene; 1,11-dodecadiene; 1,13-tetradecadiene; and

[0029] 1,19-eicosadiene.

[0030] Other unsaturated hydrocarbons which can be used include α,ω-diynes of the formula CH≡C(CH₂)_(e)C≡CH; or α,ω-ene-ynes of the formula CH₂═CH(CH₂)_(e)C≡CH where e is 0-20. Some representative ═,ω-diynes are 1,3-butadiyne HC≡C—C≡CH and 1,5-hexadiyne (dipropargyl) HC≡C—CH₂CH₂—C≡CH. An example of a suitable

[0031] α,ω-ene-yne is hexene-5-yne-1 CH₂═CHCH₂CH₂C≡CH.

[0032] Silicone Oil

[0033] The term silicone oil as used herein is intended to include compounds containing a silicon atom such as (i) low molecular weight linear and cyclic volatile methyl siloxanes, and (ii) low molecular weight linear and cyclic volatile and non-volatile alkyl and aryl siloxanes. Most preferred, however, are low molecular weight linear and cyclic volatile methyl siloxanes (VMS).

[0034] VMS compounds correspond to the average unit formula (CH₃)_(j)SiO_((4-j)/2) in which j has an average value of two to three. The compounds contain siloxane units joined by ≡Si—O—Si≡ bonds. Representative units are monofunctional “M” units (CH₃)₃SiO_(1/2) and difunctional “D” units (CH₃)₂SiO_(2/2).

[0035] The presence of trifunctional “T” units CH₃SiO_(3/2) results in the formation of branched linear or cyclic volatile methyl siloxanes. The presence of tetrafunctional “Q” units SiO_(4/2) results in the formation of branched linear or cyclic volatile methyl siloxanes.

[0036] Linear VMS have the formula (CH₃)₃SiO{(CH₃)₂SiO}_(k)Si(CH₃)₃. The value of k is 0-5. Cyclic VMS have the formula {(CH₃)₂SiO}_(m). The value of m is 3-9. Preferably, these volatile methyl siloxane have a boiling point less than about 250° C. and viscosity of about 0.65 to about 5.0 mm²/s.

[0037] Representative linear volatile methyl siloxanes are hexamethyldisiloxane (MM) with a boiling point of 100° C., viscosity of 0.65 mm²/s, and formula Me₃SiOSiMe₃; octamethyltrisiloxane (MDM) with a boiling point of 152° C., viscosity of 1.04 mm²/s, and formula Me₃SiOMe₂SiOSiMe₃; decamethyltetrasiloxane (MD₂M) with a boiling point of 194° C., viscosity of 1.53 mm²/s, and formula Me₃SiO(Me₂SiO)₂SiMe₃; dodecamethylpentasiloxane (MD₃M) with a boiling point of 229° C., viscosity of 2.06 mm²/s, and formula Me₃SiO(Me₂SiO)₃SiMe₃; tetradecamethylhexasiloxane (MD₄M) with a boiling point of 245° C., viscosity of 2.63 mm²/s, and formula Me₃SiO(Me₂SiO)4SiMe₃; and hexadecamethylheptasiloxane (MD₅M) with a boiling point of 270° C., viscosity of 3.24 mm²/s, and formula Me₃SiO(Me₂SiO)₅SiMe₃.

[0038] Representative cyclic volatile methyl siloxanes are hexamethylcyclotrisiloxane (D₃) a solid with a boiling point of 134° C. and formula {(Me₂)SiO}₃; octamethylcyclotetrasiloxane (D₄) with a boiling point of 176° C., viscosity of 2.3 mm²/s, and formula {(Me₂)SiO}₄; decamethylcyclopentasiloxane (D₅) with a boiling point of 210° C., viscosity of 3.87 mm²/s, and formula {(Me₂)SiO}₅; and dodecamethylcyclohexasiloxane (D₆) with a boiling point of 245° C., viscosity of 6.62 mm²/s, and formula {(Me₂)SiO}₆.

[0039] Representative branched volatile methyl siloxanes are heptamethyl-3-{(trimethylsilyl)oxy}trisiloxane (M₃T) with a boiling point of 192° C., viscosity of 1.57 mm²/s, and formula C₁₀H₃₀O₃Si₄; hexamethyl-3,3,bis {(trimethylsilyl)oxy} trisiloxane (M₄Q) with a boiling point of 222° C., viscosity of 2.86 mm²/s, and formula C₁₂H₃₆O₄Si₅; and pentamethyl {(trimethylsilyl)oxy} cyclotrisiloxane (MD₃) with the formula C₈H₂₄O₄Si₄.

[0040] The invention also includes using low molecular weight linear and cyclic volatile and non-volatile alkyl and aryl siloxanes represented respectively by formulas R₃SiO(R₂SiO)_(n)SiR₃ and (R₂SiO)_(p). R can be alkyl groups with 2-20 carbon atoms or aryl groups such as phenyl. The value of n is 0-80, preferably 5-20. The value of p is 3-9, preferably 4-6. These polysiloxanes have a viscosity generally in the range of about 1-100 mm²/s.

[0041] Polysiloxanes can also be used where n has a value sufficient to provide siloxane polymers with a viscosity in the range of about 100-1,000 mm²/sec. Typically, n can be about 80-375. Illustrative of such polysiloxanes are polydimethylsiloxane, polydiethylsiloxane, polymethylethylsiloxane, polymethylphenylsiloxane, and polydiphenylsiloxane.

[0042] If desired, the silicone oil component can be omitted.

[0043] CATALYST

[0044] Polymerization of the ≡Si—H containing polysiloxane, the mono-alkenyl polyether, and the α,ω-diene, α,ω-diyne, or

[0045] α,ω-ene-yne, requires a catalyst to effect the reaction between the ≡SiH containing polysiloxane, the mono-alkenyl polyether, and the α,ω-unsaturated hydrocarbon. Suitable catalysts are Group VIII transition metals, i.e., the noble metals. Such noble metal catalysts are described in U.S. Pat. No. 3,923,705, incorporated herein by reference. A particularly preferred catalyst is described in Karstedt's U.S. Pat. Nos. 3,715,334 and 3,814,730, incorporated herein by reference. Karstedt's catalyst is a platinum divinyl tetramethyl disiloxane complex, typically containing about one weight percent of platinum, carried in a polydimethylsiloxane fluid or in a solvent such as toluene.

[0046] The particular catalysts used in Examples 1 and 2 appearing below were 20 μl and 200 μl portions, respectively, of Karstedt's catalyst, used as one weight percent of platinum carried in a 2.0 mm²/s polydimethylsiloxane fluid. Another preferred platinum catalyst is a reaction product of chloroplatinic acid and an organosilicon compound containing terminal aliphatic unsaturation. It is described in U.S. Pat. No. 3,419,593, incorporated herein by reference. The noble metal catalysts are used in amounts from 0.00001-0.5 parts of noble metal per 100 weight parts of ≡SiH containing polysiloxane, preferably 0.00001-0.02 parts of noble metal, most preferably 0.00001-0.002 parts of noble metal.

[0047] In preparing compositions according to the first embodiment of the invention, the following amounts of each of the components in percent by weight of the composition, can be employed:

[0048] (i) 5-60 percent by weight of the non-crosslinked silicone polyether;

[0049] (ii) optionally, 5-60 percent by weight of the cosurfactant;

[0050] (iii) 5-50 percent by weight of the ≡Si—H containing polysiloxane;

[0051] (iv) 5-50 percent by weight of the mono-alkenyl polyether;

[0052] (v) 1-10 percent by weight of the α,ω-diene, α,ω-diyne, or α,ω)-ene-yne;

[0053] (vi) optionally, 5-60 percent by weight of the silicone oil;

[0054] (vii) 1-100 parts per million of platinum catalyst; and

[0055] (viii) 10-60 percent by weight of water.

[0056] In preparing compositions according to the second embodiment of the invention, the following amounts of each of the components in percent by weight of the composition, can be employed:

[0057] (i) 1-50 percent by weight of the non-crosslinked silicone polyether;

[0058] (ii) 1-50 percent by weight of the cosurfactant;

[0059] (iii) 0.1-73.0 percent by weight of the crosslinked silicone elastomer containing no oxyalkylene units; and

[0060] (iv) 25-97.9 percent by weight of water.

[0061] Compositions made according to the invention may contain other components, as required, for preparing the compositions for particular applications. Representative of such components are, for example, (i) additives for stabilizing the composition or adjusting its viscosity such as ethanol, or water soluble polymers such as xanthan gum, guar gum, carboxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymers, hydroxyethyl cellulose, and polyoxyethylene glycol distearate; (ii) film forming agents such as polymers of radically polymerizable (meth)acrylic monomers, copolymers of silicone polymers with radically polymerizable (meth)acrylic monomers, poly(N-acylalkylene imines), poly(N-methylpyrrolidones), and silicone resins which contain fluorinated organic groups, amino groups, or silanol groups; (iii) oxidation inhibitors such as butylated hydroxyanisole (BHA), butylated hydroxy toluene (BHT), and orizanol; (iv) antifreezes such as ethanol, isopropyl alcohol, 1,3-butylene glycol, ethylene glycol, propylene glycol, and glycerol; (v) antimicrobials and preservatives such as TRICLOSAN and TRICLOCARBAN; (vi) pearlescent agents; (vii) chelating agents such as ethylene diamine tetraacetic acid, citric acid, and ethane-1-hydroxy-1,1-diphosphonic acid; (viii) UV absorbers including benzophenone derivatives such as 2-hydroxy-4-methoxy benzophenone, benzotriazole derivatives such as 2-(2′-hydroxy-5′-methylphenyl) benzotriazole, and cinnamic acid esters; (ix) colorants such as chromatogens, dyes, and pigments; (x) aerosol spray enabling agents; (xi) vitamins; (xii) hair tonics; (xiii) growth promoters; (xiv) hormones; (xv) fragrances; and (xvi) perfumes.

[0062] While mechanical equipment such as mixers, mills, homogenizers, and extruders, can be used in preparing compositions of the invention, it is most preferred to form them without application of any shearing force, as by simply handshaking the ingredients.

EXAMPLES

[0063] The following examples are set forth in order to illustrate the invention in more detail.

Example 1 Illustration of First Embodiment

[0064] An oil-in-water microemulsion containing an in situ prepared crosslinked silicone polyether was formed by combing and handshaking the following ingredients in a sealed vial:

[0065] a. 2.4983 gram of a non-crosslinked silicone polyether having the formula MD₂₂D′₂M where M is (CH₃)₃SiO—, D is (CH₃)₂SiO═, and D′ is (CH₃)(EO₁₂PO₁₂)SiO═;

[0066] b. 2.5224 gram of the cosurfactant di(ethylene)glycol hexyl ether of the formula CH₃(CH₂)₅OCH₂CH₂OCH₂CH₂OH;

[0067] c. 2.5633 gram of deionized water;

[0068] d. 0.2767 of the ≡Si—H containing polysiloxane of the formula MD_(8.7)D′_(3.7)M where M is (CH₃)₃SiO—, D is (CH₃)₂SiO═, and D′ is (CH₃)(H)SiO≡;

[0069] e. 2.0010 gram of the volatile silicone oil D₅, i.e., decamethylcyclopentasiloxane;

[0070] f. 0.1967 gram of the mono-alkenyl polyether of the formula CH₂═CHCH₂O(CH₂CH₂O)₁₂H;

[0071] g. 0.0270 gram of platinum catalyst;

[0072] h. 0.065 gram of the α,ω-diene compound 1,5-hexadiene, i.e., CH₂═CH(CH₂)₂CH═CH₂.

[0073] The sealed vial and its contents were placed in an oven for one hour at 90° C. to initiate the polymerization reaction, forming a suspension of cured particles of a crosslinked silicone polyether in water.

Example 2 Illustration of second Embodiment

[0074] An oil-in-water microemulsion containing cured particles of a crosslinked silicone elastomer having no oxyalkylene units in its molecule, was formed by adding the following ingredients to a vial:

[0075] a. 4.9891 gram of a crosslinked silicone elastomer having no oxyalkylene units in its molecule. The crosslinked silicone elastomer was swollen with about 86.5 percent by weight of volatile silicone oil decamethylcyclopentasiloxane. The D₅ swollen elastomer was prepared by reacting (i) ≡Si—H containing polysiloxane MD_(8.7)D′_(3.7)M where M is (CH₃)₃SiO—, D is (CH₃)₂SiO═, and D′ is (CH₃)(H)SiO═, with (ii) α,ω-diene 1,5-hexadiene. The reaction was carried out in the presence of D₅ according to the method in U.S. Pat. No. 5,654,362 (Aug. 5, 1997).

[0076] b. 5.0145 gram of non-crosslinked silicone polyether MD₂₂D′₂M where M is (CH₃)₃SiO—, D is (CH₃)₂SiO═, and D′ is (CH₃)(EO₁₂PO₁₂)SiO═;

[0077] c. 2.5532 gram of cosurfactant di(ethylene)glycol hexyl ether; and

[0078] d. 5.0613 gram of deionized water.

[0079] The vial and its contents were handshaken for one minute, in order to disperse the cured particles of crosslinked silicone elastomer, in water.

[0080] The crosslinked silicone elastomer having no oxyalkylene units in its molecule, used in Example 2, is a material typically referred to in the art, as a non-emulsifying silicone elastomer, meaning that polyoxyalkylene units are absent.

[0081] Compositions prepared according to the invention can be used in various over-the-counter (OTC) personal care products. Thus, they can be used in antiperspirants, deodorants, skin creams, skin care lotions, moisturizers, facial treatments such as acne or wrinkle removers, personal and facial cleansers, bath oils, perfumes, colognes, sachets, sunscreens, pre-shave and after-shave lotions, liquid soaps, shaving soaps, shaving lathers, hair shampoos, hair conditioners, hair sprays, mousses, permanents, depilatories, cuticle coats, make-ups, color cosmetics, foundations, blushes, lipsticks, lip balms, eyeliners, mascaras, oil removers, color cosmetic removers, and powders. The compositions are also useful as carriers for pharmaceuticals, biocides, herbicides, pesticides, and to incorporate water and water-soluble substances into hydrophobic systems.

[0082] Other variations may be made in compounds, compositions, and methods described herein without departing from the essential features of the invention. The embodiments of the invention specifically illustrated herein are exemplary only and not intended as limitations on their scope except as defined in the appended claims. 

1. A method of making oil-in-water emulsions comprising mixing (i) 1-50 percent by weight of a non-crosslinked silicone polyether; (ii) 1-50 percent by weight of a cosurfactant selected from the group consisting of monohydroxy alcohols, diols, triols, and glycol ethers; and (iii) 25-97.9 percent by weight of water; with (iv) 0.1-73.0 percent by weight of a crosslinked silicone elastomer containing no oxyalkylene units prepared by reacting (a) an ≡Si—H containing polysiloxane; (b) an α,ω-diene, α,ω-diyne, or α,ω-ene-yne; (c) a silicone oil selected from the group consisting of (I) low molecular weight linear and cyclic volatile methyl siloxanes, and (II) low molecular weight linear and cyclic volatile and non-volatile alkyl and aryl siloxanes; and (d) a platinum catalyst.
 2. A method according to claim 1 in which the cosurfactant is selected from the group consisting of 1-butanol, 1-pentanol, 1-decanol, 1-hexadecanol, ethylene glycol, propylene glycol, trimethylene glycol, glycerol, and di(ethylene) glycol hexyl ether.
 3. A method according to claim 1 in which the emulsion is prepared without application of any mechanical shearing force.
 4. An emulsion prepared according to the method defined in claim
 1. 